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High-Temperature Spin Crossover in a Mononuclear Six-Coordinate Cobalt(II) Complex

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posted on 06.10.2014, 00:00 by Joanna Palion-Gazda, Anna Świtlicka-Olszewska, Barbara Machura, Thais Grancha, Emilio Pardo, Francesc Lloret, Miguel Julve
The six-coordinate cobalt­(II) complex of formula [Co­(tppz)2]­(tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.