ic035451+_si_001.cif (161.24 kB)

Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)

Name: Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)
Published: 2004-07-12T00:00:00+00:00
License: https://creativecommons.org/licenses/by-nc/4.0/
Keywords: ferrocene, thiosemicarbazone, Functionalized Thiosemicarbazone Clusters, phenol, hexanuclear clusters, substituent, pyridine, Ag, tetranuclear, Cu

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posted on 2004-07-12, 00:00 authored by Laura J. Ashfield, Andrew R. Cowley, Jonathan R. Dilworth, Paul S. Donnelly

Reaction of [Cu(MeCN)₄]⁺ with thiosemicarbazones bearing groups such as phenol, pyridine, or ferrocene gives tetranuclear or hexanuclear clusters with functional substituents; analogous air stable fluorescent clusters can also be prepared with Ag(I).

Functionalized Thiosemicarbazone Clusters of Copper(I) and Silver(I)

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