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Electronic Communication between Two Amine Redox Centers Bridged by a Bis(terpyridine)ruthenium(II) Complex

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posted on 01.08.2011, 00:00 by Chang-Jiang Yao, Jiannian Yao, Yu-Wu Zhong
Two bis(terpyridine)ruthenium(II) complexes 2 and 3 appended with one or two di-p-anisylamino groups, respectively, were synthesized and fully characterized. Their electronic properties were studied by electrochemical and spectroscopic analyses. Electronic communication between individual amine sites of 3 was estimated by intervalence charge-transfer band analyses.