Copper(I)-Catalyzed Intramolecular Trifluoromethylation of Methylenecyclopropanes
datasetposted on 18.12.2015, 00:00 by Zi-Zhong Zhu, Kai Chen, Liu-Zhu Yu, Xiang-Ying Tang, Min Shi
Datasets usually provide raw data for analysis. This raw data often comes in spreadsheet form, but can be any collection of data, on which analysis can be performed.
Copper(I)-catalyzed intramolecular trifluoromethylation of methylenecyclopropanes has been developed to produce a variety of CF3-substituted dihydronaphthalenes in moderate to good yields, relying on the construction of C(sp2)–CF3 bonds under mild conditions. The reactions proceed through a radical process under copper(I) catalysis with a good compatibility for the functional group.