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Application of Open Chain Tetraimidazolium Salts as Precursors for the Synthesis of Silver Tetra(NHC) Complexes

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posted on 20.01.2015, 00:00 by Daniel T. Weiss, Stefan Haslinger, Christian Jandl, Alexander Pöthig, Mirza Cokoja, Fritz E. Kühn
The synthesis of 3-((1H-imidazol-1-yl)­methyl)-1-methyl-1H-imidazol-3-ium iodide 1 for the synthesis of multidentate tetra-N-heterocyclic carbene (NHC) structures is described. Two acyclic open chain tetra­(NHC) precursors are synthesized together with their corresponding silver complexes. On the basis of nuclear magnetic resonance (NMR) spectroscopy and single crystal X-ray diffraction (XRD) data, the coordination geometry of the silver complexes is discussed. Dependent on the length of the alkyl bridge of the tetradentate ligand either a double helix structure with four linear-coordinated silver cations or a twisted geometry with two linear-coordinated silver cations is obtained.

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