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Allenyl Azide Cycloaddition Chemistry. Synthesis of Annelated Indoles from 2-(Allenyl)phenyl Azide Substrates

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posted on 2006-07-06, 00:00 authored by Ken S. Feldman, Malliga R. Iyer, D. Keith Hester
Thermolysis of 2-(allenyl)phenyl azides leads to a cascade cyclization sequence furnishing both C(2)−C(3) and N−C(2) cyclopentannelated indoles.