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Aerobic Oxidative Amination of Unactivated Alkenes Catalyzed by Palladium

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posted on 2005-03-09, 00:00 authored by Jodie L. Brice, Jenna E. Harang, Vitaliy I. Timokhin, Natia R. Anastasi, Shannon S. Stahl
The first examples of palladium-catalyzed oxidative amination of unactivated alkyl olefins have been identified. To be successful, these reactions must be conducted under cocatalyst-free conditions that involve direct dioxygen-coupled turnover of the palladium catalyst. The oxidative amination products of norbornene and other cyclic alkenes implicate a cis-aminopalladation mechanism.