A Pair of Rare Three-Dimensional Chiral Polyoxometalate-Based Metal–Organic Framework Enantiomers Featuring Superior Performance as the Anode of Lithium-Ion Battery
datasetposted on 2018-08-14, 00:00 authored by Weiwei Cheng, Feng-Cui Shen, Yun-shan Xue, Ximing Luo, Min Fang, Ya-Qian Lan, Yan Xu
Two rare three-dimensional (3D) chiral polyoxometalate-based metal–organic framework (POMOF) materials, d- [PMo8VMo4VIO37(OH)3Zn4][BPP]2·2[pyridine]·H2O (d-1) and l-[PMo8VMo4VIO37(OH)3Zn4][BPP]2·2[pyridine]·H2O (l-1) (BPP = 1,3-bis(4-pyridyl)propane) were prepared with achiral ligand under solvothermal conditions. They are the first 3D chiral POM-based frameworks based on a Zn-ε-Keggin unit and achiral ligands. The CD spectra and structural analyses indicate that the two polyoxometalate-based metal–organic frameworks are enantiomers. The alternate connection of Zn-ε-Keggin cluster and BPP ligands generate helical infinite chains, while each single spiral chain is further interlinked to adjacent neighboring units to produce a 3D regular ordered chiral architecture with a qtz topology. Compound 1 (mixtures of d-1 and l-1) exhibited excellent stability in both acid and base aqueous solutions. When compound 1 was used as an anode electrode material of rechargeable Li-ion batteries (LIBs), outstanding reversible capacity of 1004 mA h g–1 was obtained after 100 cycles along with cycle stability and outstanding rate performance. Such a high reversible capacity has previously never been reported for the LIB anodes within the pristine POM-based crystals.
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compound 1Zn -ε-Keggin clusterachiral ligandscycle stabilitysolvothermal conditions3 D chiral POM-based frameworksOHPMo 8 V Mo 4 VI O 37CD spectracapacityLIB anodesBPP ligandsqtz topologyPOM-based crystalsLithium-Ion Batterychiral architectureanode electrode materialpolyoxometalate-basedrate performance3 Dachiral ligandspiral chainCompound 1100 cyclesPOMOFpyridineZn -ε-Keggin unitLi-ion batteries