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A 3D CuII Coordination Framework with μ4-/μ2-Oxalato Anions and a Bent Dipyridyl Coligand: Unique Zeolite-Type NiP2 Topological Network and Magnetic Properties

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posted on 01.08.2011, 00:00 by Miao Du, Zhi-Hui Zhang, Cheng-Peng Li, Jordi Ribas-Ariño, Núria Aliaga-Alcalde, Joan Ribas
The reaction of copper(II) nitrate, oxamide, and an angular bridging ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (4-bpo) under hydrothermal conditions affords a 3D pillared-layer coordination framework {[Cu2(4-bpo)(ox)2](H2O)4}n (1) (ox = oxalate), featuring the unique zeolite-type NiP2 network and interesting properties.