ic7b00610_si_001.pdf (1.37 MB)
m‑Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers
journal contribution
posted on 2017-04-25, 12:33 authored by Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo-Lazarte, Matti Haukka, Francesc TeixidorThe first examples
of coordination polymers of manganese(II) and a nickel(II) complex
with a purely inorganic carboranylphosphinate ligand are reported,
together with its exhaustive characterization. X-ray analysis revealed
1D polymeric chains with carboranylphosphinate ligands bridging two
manganese(II) centers. The reactivity of polymer 1 with
water and Lewis bases has also been studied.