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m‑Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers

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posted on 2017-04-25, 12:33 authored by Elena Oleshkevich, Clara Viñas, Isabel Romero, Duane Choquesillo-Lazarte, Matti Haukka, Francesc Teixidor
The first examples of coordination polymers of manganese­(II) and a nickel­(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese­(II) centers. The reactivity of polymer 1 with water and Lewis bases has also been studied.

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