<i>m</i>‑Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers
2017-04-25T12:33:25Z (GMT) by
The first examples of coordination polymers of manganese(II) and a nickel(II) complex with a purely inorganic carboranylphosphinate ligand are reported, together with its exhaustive characterization. X-ray analysis revealed 1D polymeric chains with carboranylphosphinate ligands bridging two manganese(II) centers. The reactivity of polymer <b>1</b> with water and Lewis bases has also been studied.