(Pentamethylcyclopentadienyl)samarium(II) Alkyl
Complex with the Neutral “C5Me5K” Ligand:  A
Precursor to the First Dihydrido Lanthanide(III)
Complex and a Precatalyst for Hydrosilylation of
Olefins

Hou, Zhaomin; Zhang, Yugen; Tardif, Olivier; Wakatsuki, Yasuo

doi:10.1021/ja010555+.s001

ja010555+_si_001.pdf (628.23 kB)

(Pentamethylcyclopentadienyl)samarium(II) Alkyl Complex with the Neutral “C₅Me₅K” Ligand: A Precursor to the First Dihydrido Lanthanide(III) Complex and a Precatalyst for Hydrosilylation of Olefins

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posted on 2001-08-24, 00:00 authored by Zhaomin Hou, Yugen Zhang, Olivier Tardif, Yasuo Wakatsuki

(Pentamethylcyclopentadienyl)samarium(II) Alkyl Complex with the Neutral “C₅Me₅K” Ligand: A Precursor to the First Dihydrido Lanthanide(III) Complex and a Precatalyst for Hydrosilylation of Olefins

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Ligand Hydrosilylation Dihydrido Complex Precatalyst Lanthanide Olefin Pentamethylcyclopentadienyl Precursor Neutral Alkyl First

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(Pentamethylcyclopentadienyl)samarium(II) Alkyl Complex with the Neutral “C5Me5K” Ligand: A Precursor to the First Dihydrido Lanthanide(III) Complex and a Precatalyst for Hydrosilylation of Olefins

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(Pentamethylcyclopentadienyl)samarium(II) Alkyl Complex with the Neutral “C₅Me₅K” Ligand: A Precursor to the First Dihydrido Lanthanide(III) Complex and a Precatalyst for Hydrosilylation of Olefins