am8b07428_si_001.pdf (1.87 MB)
Wet-Chemical Synthesis of Surface-Passivated Halide Perovskite Microwires for Improved Optoelectronic Performance and Stability
journal contribution
posted on 2018-12-09, 15:13 authored by Qian Ye, Jin Zhang, Pengfei Guo, Haibo Fan, Dmitry Shchukin, Bingqing Wei, Hongqiang WangOne-dimensional (1D) halide perovskite
materials with intrinsic
high carrier mobility and long diffusion length hold great promises
for high-performance optoelectronic devices, in which the passivation
of the surface defects is of significance for further boosting its
optoelectronic performance as well as its moisture stability. Herein,
we demonstrate a simple room-temperature wet-chemical synthetic protocol
for perovskite microwires with controlled morphologies and passivated
surface states. This strategy allows for facile assembly of hydrophobic
1H,1H-perfluorooctylamine (PFA)
molecules on the surface of the perovskite microwires owing to the
coordination binding between the amino groups of PFA and Pb2+. Both steady and time-resolved photoluminescence measurements revealed
that the passivation of PFA greatly benefit for the inhibition of
the photogenerated carriers recombination. The constructed perovskite
microwire-based photodetectors have shown increased detectivity of
4.99 × 1011 jones and responsivity of 1.27 A/W (light
power density of 1 mW/cm2). Moreover, the hydrophobic fluorocarbon
alkyl chains endow the perovskite microwires with higher resistance
toward moisture. Such coating of a water-resisting layer resulted
in greatly enhanced stability of perovskite microwires under the humidity
of 55 ± 5% over 30 days. We thus believe that our work is of
importance for the development of 1D halide perovskite photodetectors
with highly improved performance and stability.
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stabilityfluorocarbon alkyl chainspassivated surface stateslight power densitytime-resolved photoluminescence measurementsSurface-Passivated Halide Perovskite Microwiresphotogenerated carriers recombinationperovskite microwires1 D halide perovskite photodetectorsPFAhalide perovskite materialsperovskite microwire-based photodetectors
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