om050965x_si_002.pdf (237.91 kB)
Vanadocene-Mediated Ionization of Water in the Aqua Species [H2O·B(C6F5)3]: Structural Characterization of the Hydride and Hydroxide Complexes [Cp2V(μ-H)B(C6F5)3] and [Cp2V(μ-OH)B(C6F5)3]
journal contribution
posted on 2006-03-27, 00:00 authored by Robert Choukroun, Christian Lorber, Laure Vendier, Christine LepetitThe reaction of Cp2V with B(C6F5)3 in the presence
of water leads to the hydride complex [Cp2V(μ-H)B(C6F5)3] (1)
and the hydroxide complex [Cp2V(μ-OH)B(C6F5)3] (2), both of
which have been characterized by X-ray structure determinations. Both complexes are derived from the ionization of water
in the presence of B(C6F5)3.