Unusual mixed silica–carbonate deposits from magmatic–hydrothermal hot springs, Savo, Solomon Islands

<p>The volcanic island of Savo, Solomon Islands, hosts an active hydrothermal system discharging unusual alkaline (pH 7–8) sulphate-rich, chloride-poor fluid, with variable admixtures of Ca–Mg–HCO<sub>3</sub><sup>−</sup>-rich fluid. Hot springs and their outflow streams precipitate a variety of deposits, including travertine, silica sinter and unusual mixed silica–carbonate rocks. Travertine fabrics are dominated by ray-crystal calcite, associated with rapid abiotic precipitation from a supersaturated solution. Sinter is produced by evaporation of thermal waters, and downstream samples contain preserved traces of micro-organisms, which potentially acted as templates for precipitation. Trace element chemistry of sinters and travertines includes anomalously high levels of Te, indicating a magmatic origin for a component fluid in the hydrothermal system. Springs are close to or at saturation with both calcite and amorphous silica. Increased contributions from the Ca–Mg–HCO<sub>3</sub><sup>−</sup> end-member favours calcite formation; this fluid is of low-temperature origin, and as such is favoured by high rainfall. Mixed samples show cyclical changes between silica and carbonate precipitation, potentially as a result of seasonal variation in rainfall. </p>