Unusual Reaction of Chloramine-T with
Araldoximes

Padmavathi, V.; Venugopal Reddy, K.; Padmaja, A.; Venugopalan, P.

doi:10.1021/jo020473j.s001

jo020473j_si_001.pdf (695.39 kB)

Unusual Reaction of Chloramine-T with Araldoximes

journal contribution

posted on 2003-01-09, 00:00 authored by V. Padmavathi, K. Venugopal Reddy, A. Padmaja, P. Venugopalan

Reaction of araldoximes with 4 equiv of chloramine-T in refluxing methanol produces N-(p-tolyl)-N-(p-tosyl)benzamides via addition of 2 equiv of chloramine-T to the intermediate nitrile oxide followed by extrusion of sulfur dioxide.

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Keywords

nitrile oxide 2 equiv tolyl araldoxime Unusual Reaction tosyl Araldoximes Reaction refluxing methanol 4 equiv extrusion sulfur dioxide

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