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Unexpected formation of β, meso-directly linked diporphyrins under Adler–Longo reaction conditions
journal contribution
posted on 2018-07-12, 15:59 authored by Baris Temelli, Hilal KalkanUnexpected formation of β, meso-directly linked diporphyrin products has been described in the reactions of β-formyl porphyrins with pyrrole under Adler–Longo reaction conditions. Preliminary mechanistic studies indicates that β-dipyrromethane substituted porphyrin structure is the crucial intermediate for the formation of diporphyrin product.