ja0660047_si_002.cif (59.36 kB)
TCNQ Dianion-Based Coordination Polymer Whose Open Framework Shows Charge-Transfer Type Guest Inclusion
dataset
posted on 2006-12-27, 00:00 authored by Satoru Shimomura, Ryotaro Matsuda, Takashi Tsujino, Takashi Kawamura, Susumu KitagawaA three-dimensional coordination framework constructed with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) diainon has been synthesized and structurally characterized. This open framework possessing a highly electron-rich surface has an optical sensing cavity for several aromatics with crystal-to-crystal transformation and strong accommodation, which are based on a charge-transfer interaction with them.