ic501801f_si_002.cif (35.77 kB)
Synthesis of Two Triarylboron-Functionalized Metal–Organic Frameworks: In Situ Decarboxylic Reaction, Structure, Photoluminescence, and Gas Adsorption Properties
dataset
posted on 2014-10-20, 00:00 authored by Xiaoqing Wang, Jie Yang, Liangliang Zhang, Fuling Liu, Fangna Dai, Daofeng SunTwo 3D noninterpenetrating porous
metal–organic frameworks (PMOFs) [Cd3(L1)2(DMA)2]·DMA [1, H3L1 = tris(p-carboxylic
acid)tridurylborane]
and [Zn3(L2)3(H2O)2]·5H2O·2EtOH [2, H2L2 = 4,4′-((2,3,5,6-tetramethylphenyl)boranediyl)bis(2,3,5,6-tetramethylbenzoic
acid)] were synthesized by employment of a C3-symmetric ligand (H3L1) to assembly with Cd(NO3)2 or Zn(NO3)2. Complex 1 exhibits a (3, 6)-connected
topological network based on a Cd3 cluster and Y-shaped
trinodal organic linker. Complex 2 shows a 6-connected
topology, since in situ decarboxylic reaction of the initial H3L1 occurred to generate a new ligand,
H2L2, which can be considered as
a linear linker. Both 1 and 2 exhibit blue
fluorescence. Significantly, complex 1 with larger channels
is unstable upon the removal of guest molecules. In contrast, activated 2 exhibits higher stability and permanent porosity.