Synthesis of Tris(ɣ-oximinoalkyl)amines, New Tripodal N4 Ligands

S. Dorokhov, Valentin; Jung, Hoimin; A. Andreev, Yury; Semakin, Artem N.; Oh, Jinho; Sukhorukov, Alexey Yu.; Ioffe, Sema L.; E. Semenov, Sergey; Kang, Gyumin

doi:10.6084/m9.figshare.1314931.v2

lsyc_a_1021424_sm0401.pdf (638.67 kB)

Synthesis of Tris(ɣ-oximinoalkyl)amines, New Tripodal N4 Ligands

Version 2 2015-04-16, 21:16

Version 1 2015-04-16, 21:16

journal contribution

posted on 2015-04-16, 21:16 authored by Valentin S. Dorokhov, Hoimin Jung, Yury A. Andreev, Artem N. Semakin, Jinho Oh, Alexey Yu. Sukhorukov, Sema L. Ioffe, Sergey E. Semenov, Gyumin Kang

An original approach to the synthesis of tris(γ-oximinoalkyl)amines was proposed. The suggested synthetic sequence is based on aza-Michael addition of ammonia to methyl vinyl ketone and oximation of obtained products with hydroxylamine or O-alkhylhydroxylamines. The tris(γ-oximinoalkyl)amines may be considered as prospective N4 tripodal ligands.