ol400730n_si_003.cif (16.98 kB)
Synthesis of Dibenzo[b,f]silepins with a Benzoquinolyl Ligand
dataset
posted on 2013-05-17, 00:00 authored by Yuichiro Tokoro, Kazuo Tanaka, Yoshiki ChujoA benzo[h]quinolyl ligand provided pentacoordinate character for silicon in dibenzo[b,f]silepins. Substituents on the silicon center determined both conformations of the dibenzosilepin and luminescence properties in relation to charge transfer.