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Synthesis of Dibenzo[b,f]silepins with a Benzoquinolyl Ligand

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posted on 2013-05-17, 00:00 authored by Yuichiro Tokoro, Kazuo Tanaka, Yoshiki Chujo
A benzo[h]quinolyl ligand provided pentacoordinate character for silicon in dibenzo[b,f]silepins. Substituents on the silicon center determined both conformations of the dibenzosilepin and luminescence properties in relation to charge transfer.

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