ic052139m_si_003.cif (19 kB)

Synthesis and Characterization of Aluminum-Containing Tin(IV) Heterobimetallic Sulfides

dataset

posted on 2006-04-17, 00:00 authored by Zhi Yang, Xiaoli Ma, Vojtech Jancik, Zhensheng Zhang, Herbert W. Roesky, Jörg Magull, Mathias Noltemeyer, Hans-Georg Schmidt, Raymundo Cea-Olivares, Rubén A. Toscano

Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)₂(THF)₂]₂ (1) [L = HC(CMeNAr)₂, Ar = 2,6-iPr₂C₆H₃] with Ph₂SnCl₂, Me₂SnCl₂, and SnCl₄ in THF respectively afforded LAl(μ-S)₂SnPh₂ (2), LAl(μ-S)₂SnMe₂ (3), and LAl(μ-S)₂Sn(μ-S)₂AlL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.