ol200412r_si_001.cif (12.52 kB)
Stereoselective Direct Amine-Catalyzed Decarboxylative Aldol Addition
dataset
posted on 2011-04-01, 00:00 authored by Kerstin Rohr, Rainer MahrwaldA stereoselective decarboxylative aldol addition of β- and α-keto acids in the presence of catalytic amounts of amines is described. By the optional deployment of chiral enolizable aldehydes an access to enantiopure configurative defined ketopentoses, ketohexoses, or ketoheptoses is given.