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Stereodivergent Synthesis of Pseudotabersonine Alkaloids

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posted on 2017-09-13, 14:33 authored by Mihail Kazak, Martins Priede, Kirill Shubin, Hannah E. Bartrum, Jean-François Poisson, Edgars Suna
An eight-step stereodivergent synthesis of enantiomerically pure (−)-14-epi-pseudo­tabersonine and (+)-pseudotabersonine has been developed from a common N-tert-butane­sulfinyl ketimine key intermediate.

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    Stereodivergent Synthesisepi-pseudoeight-step stereodivergent synthesisketiminePseudotabersonine Alkaloidsenantiomericallypseudotabersoninetert

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