jp311206e_si_001.pdf (595.32 kB)
Size-Dependent Extinction Coefficients and Transition Energies of Near-Infrared β‑Ag2Se Colloidal Quantum Dots
journal contribution
posted on 2013-03-14, 00:00 authored by Marc-Antoine Langevin, Dany Lachance-Quirion, Anna M. Ritcey, Claudine Nì. AllenOur investigations of silver selenide
colloidal quantum dots, emitting
in the biologically important near-infrared region, demonstrate the
size-dependence of their optical properties. Ag2Se nanocrystals
were prepared in the orthorhombic phase with their average radius
varying from 0.95 to 4.7 nm as observed by transmission electron microscopy.
The high purity of the samples, established by energy-dispersive X-ray
spectroscopy and X-ray diffraction, allowed for the accurate determination
of the Ag2Se content of colloidal suspensions by a thermogravimetric
method. The energy of the first observed transition is found to decrease
asymptotically with colloidal quantum dot size, tending toward a value
of 1.1 eV, a value significantly above the β-Ag2Se
bulk bandgap. Furthermore, the molar extinction coefficient of this
absorption is proportional to r02.7±0.2, where r0 is the cQD radius. At higher
energies, the extinction coefficient eventually follows the classically
predicted cubic power law with r0.