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Silver Nanoparticle-Doped 3D Porous Carbon Nanofibers as Separator Coating for Stable Lithium Metal Anodes
journal contribution
posted on 2019-04-24, 00:00 authored by Min Liu, Nanping Deng, Jingge Ju, Liyuan Wang, Gang Wang, Yali Ma, Weimin Kang, Jing YanThe ever-increasing
demand for electric devices and vehicles prompts the fast development
of energy storage systems. Lithium metal is thought to be the most
promising electrode for high-performance batteries. However, the growth
of lithium dendrites impedes the industrial production of lithium
metal batteries. Herein, an effective approach is proposed by coating
a commercial separator with three-dimensional porous carbon fibers
loaded with silver nanoparticles (Ag-PCNFs), which can be regarded
as a subsidiary of the electrode to improve the cycling performance
of lithium metal batteries. The porous structure with a high specific
surface area endows the electrode with a high lithium-loading capacity.
The silver nanoparticles provide the electrode pro-Li property and
excellent electrical conductivity, which are beneficial for the electrochemical
reaction and reduce the local current density to attain a dendrite-free
electrode. Electrochemical cycling performance of symmetric Li–Li
batteries shows that Ag-PCNF coating can hinder dendrite growth and
enhance the cycling stability, indicating that Ag-PCNFs acting as
host materials can effectively guide the deposition of Li and solve
the dendrite problem.