ol7b02706_si_001.pdf (9.14 MB)
Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant
journal contribution
posted on 2017-10-18, 14:18 authored by Jordan
D. Galloway, Duy N. Mai, Ryan D. BaxterA new
method for silver-catalyzed Minisci reactions using Selectfluor
as a mild oxidant is reported. Heteroarenes and quinones both participate
in radical C–H alkylation and arylation from a variety of carboxylic
and boronic acid radical precursors. Several oxidatively sensitive
and highly reactive radical species are successful, providing structures
that are challenging to access by other means.