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Shape Control of Zn(II) Metal–Organic Frameworks by Modulation Synthesis and Their Morphology-Dependent Catalytic Performance

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journal contribution
posted on 2015-05-06, 00:00 authored by Mohammad Yaser Masoomi, Saeideh Beheshti, Ali Morsali
Micro- and nanorods and plates of three porous Zn­(II)-based metal–organic frameworks, [Zn2(oba)2(4-bpdb)]n·2­(DMF) (TMU-4), [Zn­(oba)­(4-bpdh)0.5]n·1.5­(DMF) (TMU-5), and [Zn­(oba)­(4-bpmb)0.5]n 1.5­(DMF) (TMU-6) were synthesized by the coordination modulation method. The effects of concentration of modulator, temperature, and time of reaction on size and morphology have been investigated. Also, catalytic performance of TMU-5 nanosized metal–organic framework in Knoevenagel condensation reaction was evaluated.

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