cg5b00304_si_001.pdf (4.45 MB)
Shape Control of Zn(II) Metal–Organic Frameworks by Modulation Synthesis and Their Morphology-Dependent Catalytic Performance
journal contribution
posted on 2015-05-06, 00:00 authored by Mohammad
Yaser Masoomi, Saeideh Beheshti, Ali MorsaliMicro-
and nanorods and plates of three porous Zn(II)-based metal–organic
frameworks, [Zn2(oba)2(4-bpdb)]n·2(DMF) (TMU-4), [Zn(oba)(4-bpdh)0.5]n·1.5(DMF) (TMU-5), and [Zn(oba)(4-bpmb)0.5]n 1.5(DMF) (TMU-6) were synthesized
by the coordination modulation method. The effects of concentration
of modulator, temperature, and time of reaction on size and morphology
have been investigated. Also, catalytic performance of TMU-5 nanosized
metal–organic
framework in Knoevenagel condensation reaction was evaluated.