cm202019b_si_001.pdf (4.58 MB)
Rapid Sol–Gel Fabrication of High-Quality Thin-Film Stacks on Planar and Curved Substrates
journal contribution
posted on 2016-02-22, 11:47 authored by Moussa Barhoum, Jacob M. Morrill, David Riassetto, Michael H. BartlA versatile and rapid sol–gel technique for the
fabrication
of high quality one-dimensional photonic bandgap materials was developed.
Silica/titania multilayer materials are fabricated by a sol–gel
chemistry route combined with dip-coating onto planar or curved substrates.
A shock-cooling step immediately following the thin-film heat-treatment
process is introduced. This step was found crucial in the prevention
of film crack formationespecially in silica/titania alternating
stack materials with a high number of layers. The versatility of this
sol–gel method is demonstrated by the fabrication of various
Bragg stack-type materials with fine-tuned optical properties by tailoring
the number and sequence of alternating layers, the film thickness
and the effective refractive index of the deposited thin films. Measured
optical properties show good agreement with theoretical simulations,
confirming the high quality of these sol–gel fabricated optical
materials.