ol7b03247_si_001.pdf (10.28 MB)
Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers
journal contribution
posted on 2017-11-18, 15:29 authored by Jianing Xie, Wusheng Guo, Aijie Cai, Eduardo C. Escudero-Adán, Arjan W. KleijA general
methodology for the synthesis of enantioenriched tertiary
allylic aryl ethers through Pd-catalyzed decarboxylative reactions
of vinyl cyclic carbonates and phenols is presented. Switching of
the regioselectivity toward the formation of linear products by a
judicious choice of the ligand is also reported.