ma501960t_si_003.avi (3.47 MB)
Patternable Conjugated Polymers with Latent Hydrogen-Bonding on the Main Chain
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posted on 2014-12-23, 00:00 authored by Kun Yang, Tianda He, Xiaoyi Chen, Stephen Z. D. Cheng, Yu ZhuConjugated polymers with latent hydrogen-bonding
on the main chain
were synthesized using Suzuki coupling reaction. The resulting polymers
with latent hydrogen-bonding can be converted to the actual hydrogen-bonded
polymers by thermal annealing or UV irradiation. As the hydrogen-bonding
sites are fused with π-conjugated units on the polymer backbone,
the intermolecular interactions between the polymer chains will be
strongly enhanced when the hydrogen-bonds are formed. By removing
the protection group and forming hydrogen-bonding, the polymers exhibited
a bathochromic shift over those with latent hydrogen-bonding, indicating
a hydrogen-bonding-mediated enhancement of π–π
stacking. In addition, the fused hydrogen-bond sites and π-conjugated
units led to closely packed polymer chains, resulting in insoluble
pigment-like polymers. This drastic solubility change from polymers
with latent hydrogen-bonding to hydrogen-bonded polymers can be used
to pattern conjugated polymers directly. The photolithography of the
conjugated polymer with latent hydrogen-bonding was demonstrated,
and the patterned electrochromic devices were fabricated and tested.