ol8b01015_si_001.pdf (5.98 MB)
Palladium-Catalyzed Ullmann Cross-Coupling of β‑Iodoenones and β‑Iodoacrylates with o‑Halonitroarenes or o‑Iodobenzonitriles and Reductive Cyclization of the Resulting Products To Give Diverse Heterocyclic Systems
journal contribution
posted on 2018-04-20, 16:21 authored by Faiyaz Khan, Michael Dlugosch, Xin Liu, Marium Khan, Martin G. Banwell, Jas S. Ward, Paul D. CarrThe palladium-catalyzed
Ullmann cross-coupling of β-iodoenones
and β-iodoacrylates such as 5 (X = I) with o-halonitroarenes and o-iodobenzonitriles
including 2 affords products such as compound 7. These can be engaged in a range of reductive cyclization reactions
leading to heterocyclic frameworks such as 3,4-benzomorphan derivative 43.
History
Usage metrics
Categories
Keywords
compound 7benzomorphanheterocyclic frameworksPalladium-Catalyzed Ullmann Cross-Couplingβ- iodoacrylatesIodoacrylateResulting ProductsHalonitroareneIodobenzonitrileReductive CyclizationIodoenonehalonitroareneDiverse Heterocyclic Systemsβ- iodoenonesiodobenzonitrilereductive cyclization reactionspalladium-catalyzed Ullmann cross-coupling
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC