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Octahedral Pt2CuNi Uniform Alloy Nanoparticle Catalyst with High Activity and Promising Stability for Oxygen Reduction Reaction
journal contribution
posted on 2015-04-03, 00:00 authored by Changlin Zhang, William Sandorf, Zhenmeng PengDevelopment of a highly active and
stable electrocatalyst is of
great significance in the oxygen reduction reaction (ORR) research.
Although octahedral Pt–Ni nanoparticle catalysts have attracted
much interest because of their high activity, their poor stability
raises a severe issue for real applications. We achieve both outstanding
ORR activity and much improved catalyst stability by preparing octahedral
Pt2CuNi alloy nanoparticles with uniform element distribution,
with the activity far exceeding the DOE target and the stability comparable
to that of state-of-the-art Pt/C. The improved stability is attributed
to uniform elemental distribution within the ternary particles, which
helps with formation of intact Pt surface layers and good retention
of the octahedral morphology.
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octahedral Pt 2CuNi alloy nanoparticlesPromising StabilityORR activityHigh Activityternary particlesoctahedral morphologyAlloy Nanoparticle Catalystcatalyst stabilityPt surface layersoxygen reduction reactionuniform element distributionDOE targetOxygen Reduction ReactionDevelopmentOctahedral Pt 2CuNi
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