ja308103g_si_004.cif (23.27 kB)
NCN Pincer–Pt Complexes Coordinated by (Nitronyl Nitroxide)-2-ide Radical Anion
dataset
posted on 2012-10-31, 00:00 authored by Xun Zhang, Shuichi Suzuki, Masatoshi Kozaki, Keiji OkadaNew pincer–Pt complexes coordinated by (nitronyl
nitroxide)-2-ide
radical anion were prepared as stable compounds in high yields. The
structures of these Pt complexes and the oxidized complexes were unequivocally
determined by spectral and crystal structure analyses. The oxidation
potential of the nitronyl nitroxide moiety in these complexes was
shifted in the negative direction by ∼0.6 V as a result of
coordination to the Pt(II) atom.
