ic050452i_si_003.cif (22.71 kB)
Microporous Pillared Paddle-Wheel Frameworks Based on Mixed-Ligand Coordination of Zinc Ions
dataset
posted on 2005-07-11, 00:00 authored by Bao-Qing Ma, Karen L. Mulfort, Joseph T. HuppThe reaction of Zn(NO3)2·6H2O, various dicarboxylic acids, and
either 4,4‘-bipyridine or N,N‘-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide produces a family of anisotropic, mixed-ligand,
open-framework compounds featuring paddle-wheel-type coordination of Zn(II) pairs in two dimensions and pyridyl ligand pillaring in
the third. Despite 2-fold interpenetration, the compounds contain
channels of molecular dimensions and several are permanently
microporous, displaying high internal surface areas.