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Micro- and Nanocrystalline Inverse Spinel LiCoVO4 for Intercalation Pseudocapacitive Li+ Storage with Ultrahigh Energy Density and Long-Term Cycling
journal contribution
posted on 2018-01-30, 00:00 authored by Haritha Hareendrakrishnakumar, Reshma Chulliyote, Mary Gladis JosephIntercalation pseudocapacitance
has been recognized as a new type of charge storage mechanism in crystalline
metal oxides, wherein Li+ intercalation is not limited
to surface structures, instead extended to the bulk crystalline framework
of the material. This may possibly narrow the performance gap between
pseudocapacitors and batteries. Hitherto, very few crystalline materials
have been found to exhibit such an intrinsic capacitive property.
Here, we report for the first time that the inverse spinel LiCoVO4 exhibits intercalation pseudocapacitive Li+ storage
property in aqueous electrolyte. Micro- and nanocrystalline LiCoVO4 were synthesized via conventional solid-state reaction and
hydrothermal reaction followed by calcination, respectively. In particular,
nanocrystalline LiCoVO4 demonstrated better Li+ intercalation benefited from its small crystallite size with highly
exposed Li+ selective crystallographic pathways toward
electrolyte. The LiCoVO4 nanocrystals demonstrated excellent
capacitive performance, including high specific capacitance (929.58
F g–1 at 1 A g–1) and cycling
stability. Moreover, asymmetric hybrid cells were assembled using
nanocrystalline LiCoVO4 and MWCNT as the positive and negative
electrode, respectively. The hybrid cells exhibited an unprecedented
energy density (148.75 Wh kg–1 at a power density
of 264.6 W kg–1) and superior cycling stability
(94% capacitance retention after 5000 cycles).
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nanocrystalline LiCoVO 4Ultrahigh Energy DensityIntercalation Pseudocapacitive LiLong-Term Cycling Intercalation pseudocapacitanceMWCNThydrothermal reactionLiCoVO 4 nanocrystalscrystallite sizespinel LiCoVO 4 exhibits intercalation pseudocapacitive Li5000 cyclescapacitive propertyperformance gapsurface structuresmetal oxidesstorage propertycapacitive performancecycling stabilitypower densityNanocrystalline Inverse Spinel LiCoVO 4charge storage mechanism
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