ja500362w_si_001.pdf (1 MB)
Metal–Organic Framework@Microporous Organic Network: Hydrophobic Adsorbents with a Crystalline Inner Porosity
journal contribution
posted on 2014-05-14, 00:00 authored by Jiseul Chun, Sungah Kang, Nojin Park, Eun Ji Park, Xing Jin, Kwang-Dae Kim, Hyun Ook Seo, Sang Moon Lee, Hae Jin Kim, Woo Hyun Kwon, Young-Kwon Park, Ji Man Kim, Young Dok Kim, Seung Uk SonThis
work reports the synthesis and application of metal–organic
framework (MOF)@microporous organic network (MON) hybrid materials.
Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous
materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid
materials float on water and show excellent performance for adsorption
of a model organic compound, toluene, in water. Chemical etching of
the MOF results in the formation of hollow MON materials.
