ol8b03356_si_001.pdf (3.78 MB)
Markovnikov-Selective Co(I)-Catalyzed Hydroboration of Vinylarenes and Carbonyl Compounds
journal contribution
posted on 2018-12-10, 19:19 authored by Piyush
Kumar Verma, Sethulekshmi A. S., K. GeetharaniAn NHC-supported
Co(I) catalyst has been developed for selective
Markovnikov hydroboration of vinylarenes under mild reaction conditions.
The hydroboration allows highly selective synthesis of a wide range
of secondary and tertiary alkyl boronates in excellent yields. Our
protocol also enables hydroboration of aldehydes and ketones with
diverse functional groups to access the corresponding borate esters.