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LnBSb2O8 (Ln = Sm, Eu, Gd, Tb): A Series of Lanthanide Boroantimonates with Unusual 3D Anionic Structures
journal contribution
posted on 2016-09-30, 19:33 authored by Dong Yan, Fei-Fei Mao, Jiang-Gao MaoA series
of lanthanide boroantimonates, namely, LnBSb2O8 (Ln = Sm 1, Eu 2, Gd 3, and
Tb 4) have been successfully synthesized by high temperature
solid-state reactions for the first time. They are isostructural and
feature novel three-dimensional (3D) frameworks composed of 2D [Sb3O12]9– layers interconnected
by 1D [SbBO7]6– chains with remaining
BO3 groups hanging on the walls of the 1D 6-membered-ring
(MR) tunnels along the a-axis, and the lanthanide
ions filled in the voids of the anionic structure. They exhibit high
thermal stability (up to 900 °C). Luminescent studies suggest
that compounds 1, 2, and 4 have potential
application as orange, red, and green light luminescent materials,
respectively. Magnetic measurements reveal ferromagnetic coupling
interactions in compound 3 and antiferromagnetic coupling
interactions between magnetic centers in compounds 1, 2, and 4.