ic8b01004_si_001.pdf (1.26 MB)
Lanthanide–Nitronyl Nitroxide Chains Derived from Multidentate Nitronyl Nitroxides
journal contribution
posted on 2018-06-13, 12:07 authored by Juan Sun, Zan Sun, Licun Li, Jean-Pascal SutterUnprecedented lanthanide
(Ln)-radical loop-chain coordination polymers were achieved using
multidentate pyridyl- or triazole- substituted nitronyl nitroxide
ligands. Their magnetic units consist of ferromagnetic [Ln2Radical] moieties, leading for the dysprosium(III) derivatives to
slow relaxation of magnetization, which was found to be dependent
on the heterocyclic ligands.