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K2Hg2Te3: Straightforward and Large-Scale Mercury-Flux Synthesis of a Small-Band-Gap Photoconducting Material

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posted on 2018-09-25, 11:41 authored by Günther Thiele, Philipp Bron, Sina Lippert, Frederik Nietschke, Oliver Oeckler, Martin Koch, Bernhard Roling, Stefanie Dehnen
K2Hg2Te3 was synthesized via a mercury-flux synthesis pathway. Single-crystal and powder X-ray diffraction reveal the compound to be isostructural to its lighter congener K2Hg2Se3, yet exhibiting enhanced photoconductivity and electrical conductivity of (several) orders of magnitude and a decreased thermal conductivity and band gap. In this report, we elaborate on the synthesis and properties of the novel ternary compound.

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