Isolation and Characterization of a Carbene Derivative of La@C<sub>82</sub>
2004-06-09T00:00:00Z (GMT) by
The photochemical reaction of La@C<sub>82</sub> with 2-adamantane-2,3-[3H]-diazirine affords adduct <b>2</b>, La@C<sub>82</sub>(Ad), in a quantitative and highly selective manner. The structure of compound <b>2</b> is confirmed by ESR, MS, and UV−vis−NIR spectroscopies, and the first X-ray crystallographic characterization of an endohedral monometallofullerene derivative is reported.
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