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Insertion of Functional Groups into a Nd3+ Metal–Organic Framework via Single-Crystal-to-Single-Crystal Coordinating Solvent Exchange

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posted on 2012-06-04, 00:00 authored by Manolis J. Manos, Eleni J. Kyprianidou, Giannis S. Papaefstathiou, Anastasios J. Tasiopoulos
Single-crystal-to-single-crystal (SCSC) transformations represent some of the most fascinating phenomena in chemistry. They are not only intriguing from a basic science point of view but also provide a means to modify or tune the properties of the materials via the postsynthetic introduction of suitable guest molecules or organic functional groups into their structures. Here, we describe UCY-2, a new flexible Nd3+ metal–organic framework (MOF), which exhibits a unique capability to undergo a plethora of SCSC transformations with some of them being very uncommon. These structural alterations involve the replacement of coordinating solvent molecules of UCY-2 by terminally ligating solvents and organic ligands with multiple functional groups including −OH, −SH, −NH–, and −NH2 or their combinations, chelating ligands, anions, and two different organic compounds. The SCSC coordinating solvent exchange is thus demonstrated as a powerful method for the functionalization of MOFs.

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