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Infrared and Computational Studies of Spontaneously Adsorbed Amine Reagents on YBa2Cu3O7: Structural Characterization of Monolayers atop Anisotropic Superconductor Surfaces
journal contribution
posted on 1998-03-13, 00:00 authored by Jason E. Ritchie, Cyndi A. Wells, Ji-Ping Zhou, Jianai Zhao, John T. McDevitt, Carl R. Ankrum, Luckner Jean, David R. KanisMethods capable of forming highly organized monolayers on top of
YBa2Cu3O7 (YBCO), a
high-Tc superconductor, have been identified and are
described for the first time. Here, grazing reflectance
infrared
fourier transform spectroscopy (GRIFTS) is employed to evaluate the
degree of order for these monolayer
structures. Through these investigations, it is found that while
octadecylamine forms a well-ordered, crystalline-like monolayer on the surface of c-axis-oriented
YBa2Cu3O7 thin films, the same
reagent adsorbed onto
polycrystalline YBa2Cu3O7
pellets affords disordered, liquid-like monolayers. Computational
studies of
alkylamine packing, using a molecular mechanics methodology, reveal two
plausible structures for the crystalline-like monolayer. A GRIFTS comparison of primary, secondary, and
tertiary alkylamine reagents also has been
completed, and the substitution pattern dependence of the monolayer
order has been assessed experimentally.
Moreover, comparisons between amine monolayers on top of
YBa2Cu3O7 and alkyl thiol
reagents on gold
surfaces are made using GRIFTS and thermal desorption experiments.
This work documents the initial report
of the assembly and characterization of organized monolayers supported
on high-Tc superconductor surfaces,
the most complex substrate yet reported capable of fostering ordered
adsorbate layers.
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mechanics methodologysubstitution pattern dependenceGRIFTS comparisonComputational studiesamine monolayersmonolayer structuresmonolayer orderdesorption experimentsalkyl thiol reagentsSpontaneously Adsorbed Amine ReagentsYBa 2 Cu 3 O 7T c superconductorgold surfacesoctadecylamine formsalkylamine reagentsYBa 2 Cu 3 O 7 pelletsComputational StudiesYBCOT c superconductor surfacesAnisotropic Superconductor Surfaces Methodswork documentsadsorbate layers
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