ic201425v_si_001.pdf (193.66 kB)
In Situ Formed White-Light-Emitting Lanthanide–Zinc–Organic Frameworks
journal contribution
posted on 2016-02-22, 06:50 authored by Shu-Mu Li, Xiang-Jun Zheng, Da-Qiang Yuan, Ayjamal Ablet, Lin-Pei JinFive novel 3D heterometallic lanthanide–zinc–organic
frameworks, [H(H2O)8][LnZn4(imdc)4(Him)4] [Ln = La (1), Pr (2), Eu (3), Gd (4), Tb (5);
H3imdc = 4,5-imidazoledicarboxylic acid; Him = imidazole],
were synthesized via an in situ hydrothermal reaction, and tunable
luminescence from yellow to white was obtained through the doping
of Eu and Tb ions in the La–Zn framework.