jo7b01608_si_003.cif (555.37 kB)
Hypervalent Iodonium Alkynyl Triflate Generated Phenylcyanocarbene and Its Reactivity with Aromatic Systems
dataset
posted on 2017-08-25, 00:00 authored by Mohammed
H. Al-Huniti, Zachary B. Sullivan, Jarrod L. Stanley, James A. Carson, I. F. Dempsey Hyatt, A. Christina Hairston, Mitchell P. CroattPhenylcyanocarbene
was generated by the reaction of azide with
a hypervalent iodonium alkynyl triflate and reacted in situ with 21 different carbocyclic and heterocyclic aromatic compounds.
These reactions led to more complex products that frequently underwent
subsequent rearrangements. The reactivity was further explored in
a mechanistic study to ascertain the chemoselectivity and stereospecificity.