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Formation of Ethylene-Bridged Dinuclear IrIII Species via M−C Coupling of IrII and IrII(ethene)

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posted on 2002-09-20, 00:00 authored by Bas de Bruin, Simone Thewissen, Tsi-Wai Yuen, Theo P. J. Peters, Jan M. M. Smits, Anton W. Gal
Ethene dissociation from [(Mentpa)IrII(ethene)]2+, induced by coordination of acetonitrile, causes a rapid and selective M−C coupling between IrII and IrII(ethene), resulting in ethylene-bridged dinuclear iridium(III) complexes of the composition [{(Mentpa)IrIII(NCMe)}22-C2H4)]4+ (n = 2, 3).

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