es5b02562_si_001.pdf (329.95 kB)
Fate of Soil Organic Carbon and Polycyclic Aromatic Hydrocarbons in a Vineyard Soil Treated with Biochar
journal contribution
posted on 2015-09-15, 00:00 authored by Alessandro
G. Rombolà, Will Meredith, Colin
E. Snape, Silvia Baronti, Lorenzo Genesio, Francesco Primo Vaccari, Franco Miglietta, Daniele FabbriThe effect of biochar addition on
the levels of black carbon (BC)
and polcyclic aromatic hydrocarbons (PAHs) in a vineyard soil in central
Italy was investigated within a two year period. Hydropyrolysis (HyPy)
was used to determine the contents of BC (BCHyPy) in the
amended and control soils, while the hydrocarbon composition of the
semi-labile (non-BCHyPy) fraction released by HyPy was
determined by gas chromatography–mass spectrometry, together
with the solvent-extractable PAHs. The concentrations of these three
polycyclic aromatic carbon reservoirs changed and impacted differently
the soil organic carbon over the period of the trial. The addition
of biochar (33 ton dry biochar ha–1) gave rise to
a sharp increase in soil organic carbon, which could be accounted
for by an increase in BCHyPy. Over time, the concentration
of BCHyPy decreased significantly from 36 to 23 mg g–1 and as a carbon percentage from 79% to 61%. No clear
time trends were observed for the non-BCHyPy PAHs varying
from 39 to 34 μg g–1 in treated soils, not
significantly different from control soils. However, the concentrations
of extractable PAHs increased markedly in the amended soils and decreased
with time from 153 to 78 ng g–1 remaining always
higher than those in untreated soil. The extent of the BCHyPy loss was more compatible with physical rather than chemical processes.