ma7b01592_si_001.pdf (1.15 MB)
Facile Polymerization of Water and Triple-Bond Based Monomers toward Functional Polyamides
journal contribution
posted on 2017-10-18, 14:23 authored by Jie Zhang, Wenjie Wang, Yong Liu, Jing Zhi Sun, Anjun Qin, Ben Zhong TangWater is an abundant, natural, and
sustainable resource. However,
it has not been used as a monomer for the construction of polymers.
In this paper, we take this challenge and develop a new polymerization
of water and triple-bond based monomers of isocyanides and bromoalkynes,
and polyamides with high molecular weights (up to 41 700) and
stereoregularities (the fraction of Z-isomer generally
higher than 80%) are obtained in excellent yields (up to 98.1%) under
mild reaction conditions. The polymers possess good solubility and
exhibit high thermal stability and refractive index. The tetraphenylethene-containing
polymers show the unique aggregation-enhanced emission (AEE) characteristics.
Moreover, thanks to their containing bromoacrylamide groups in the
main chains, these polyamides could be easily postmodified through
different reactions, providing a convenient platform for polymer functionalization.
Thus, this work not only established a stereoselective polymerization
of water and triple-bond based monomers but also provided a powerful
strategy for the preparation of functional polyamides under mild reaction
conditions.