la5b04641_si_001.pdf (2.11 MB)
Fabrication of Binder-Free Pencil-Trace Electrode for Lithium-Ion Battery: Simplicity and High Performance
journal contribution
posted on 2016-04-15, 00:00 authored by Hyean-Yeol Park, Min-Sik Kim, Tae-Sung Bae, Jinliang Yuan, Jong-Sung YuA binder-free
and solvent-free pencil-trace electrode with intercalated
clay particles (mainly SiO2) is prepared via a simple pencil-drawing
process on grinded Cu substrate with rough surface and evaluated as
an anode material for lithium-ion battery. The pencil-trace electrode
exhibits a high reversible capacity of 672 mA h g–1 at 100 mA g–1 after 100 cycles, which can be attributed
to the unique multilayered graphene particles with lateral size of
few micrometers and the formation of LixSi alloys generated by interaction between Li+ and an
active Si produced in the electrochemical reduction of nano-SiO2 in the clay particles between the multilayered graphene particles.
The multilayered graphene obtained by this process consists of 1 up
to 20 and occasionally up to 50 sheets and thus can not only help
accommodating the volume change and alleviating the structural strain
during Li ion insertion and extraction but also allow rapid access
of Li ions during charge–discharge cycling. Drawing with a
pencil on grinded Cu substrate is not only very simple but also cost-effective
and highly scalable, easily establishing graphitic circuitry through
a solvent-free and binder-free approach.