ic6b03024_si_001.pdf (2.86 MB)
Enhancement of Ferroelectricity for Orthorhombic (Tb0.861Mn0.121)MnO3−δ by Copper Doping
journal contribution
posted on 2017-02-27, 17:18 authored by Jianming Deng, Muhammad Asim Farid, Meng Zhang, Aimei Yang, Hongxing Zhang, Hao Zhang, Gengfang Tian, Meimei Wu, Laijun Liu, Junliang Sun, Guobao Li, Fuhui Liao, Jianhua LinCopper-doped (Tb0.861Mn0.121)MnO3−δ has
been synthesized by the conventional solid state reaction method.
X-ray, neutron, and electron diffraction data indicate that they crystallize
in Pnma space group at room temperature. Two magnetic
orderings are found for this series by neutron diffraction. One is
the ICAM (incommensurate canted antiferromagnetic) ordering of Mn
with a wave vector qMn = (∼0.283,
0, 0) with a ≈ 5.73 Å, b ≈ 5.31 Å, and c ≈ 7.41 Å,
and the other is the CAM (canted antiferromagnetic) ordering of both
Tb and Mn in the magnetic space group Pn′a21′ with a ≈
5.73 Å, b ≈ 5.31 Å, and c ≈ 7.41 Å. A dielectric peak around 40 K is
found for the samples doped with Cu, which is higher than that for
orthorhombic TbMnO3.